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KNEC KCSE Chemistry Paper 1 – 2014 Cross Country Mock

KNEC KCSE Chemistry Paper 1 – 2014 Cross Country Mock

2014 Cross Country Mock

Chemistry Paper 1

Answer all
1.

The table below gives some properties of gases D and E

GASES Density Effect of H2SO4 (aq) Effect of NaOH(aq)
D Lighter than air Reacts to form a salt dissolves without reacting
E Heavier than air Not affected Not affected

(a) Describe how one would obtain a sample of gas E from a mixture of gases D and E (2mks)







(b) Suggest a possible identity of gas D (1mk)








 3 marks

2.

Iron roofing sheets are coated with zinc as sacrificial metal;
(i) What is meant by the term ‘sacrificial’? (1mk)






(ii) Give the name given to the process by which iron sheets are coated with zinc. (1mk)






(iii) Zinc is higher than iron in reactivity series yet it does not corrode as fast as iron.
Explain (1mk)








 3 marks

3.

The set-up below was used to investigate the properties of hydrogen gas.

Chemistry Paper 1 Question Paper - 2014 Cross Country Mock
(i) Write an equation for the reaction that takes place in the combustion tube. (1mk)









(ii) Suggest a possible drying agent X. (½mk)







(iii) What would happen if the hydrogen gas at the end is not burnt? (1mk)








 2.5 marks

4.

The table below shows pH values of solutions A to E.

Solution A B C D E
pH 3 14 7 6 9

Which solution;
(a) Contains the largest concentration of hydroxyl ions? (1mk)






(b) Contains the largest concentration of hydrogen ions (1mk)







(c) is likely to be a solution of sodium chloride (1mk)






 3 marks

5.

Potassium is isotopic and has a relative atomic mass (R.A.M) of 39.5, work out the percentage
abundance of each isotope. The three isotopes are, 39K, 40K, and 38K (0.01%)












 3 marks

6.

An ion of element Q can be represented as 1632Q2-
(a) Draw the structure of the ion (2mks)








(b) How does its ionic radius compare with its atomic radius (1mk)







 3 marks

7.

The electronic configuration for elements represented by letters A, B, C and D are A 2.8.6, B 2.8.2, C 2.8.1, D 2.8.8.
(a) Select the element which forms;

(i) A double charged cation (1mk)



(ii) a soluble carbonate (1mk)



(b) Which element has the shortest atomic radius (1mk)



 3 marks

8.

When concentrated hydrochloric acid was electrolysed for a longtime. Two gases were
obtained at the anode ;
(i) Name the two gases (1mk)



(ii) Explain why the gases were obtained. (2mks)




 3 marks

9.

Using dots (  ) and crosses (X) to represent electrons, draw diagrams to show bonding in;
(a) C2H4 (C=12 H=1) (2mks)




(b) Hydro-oxonium ion H3O + (H=1 O=8) (2mks)




 4 marks

10.

A student reacted Silver Nitrate and Barium Chloride solutions to prepare two salts.

(i) Write an equation for the reaction that took place (1mk)





(ii) Write the ionic equation for the reaction (1mk)





(iii) Name the method above use din preparing salts mentioned. (1mk)





 3 marks

11.

Give the name and formula of;
(i) A complex cation containing a transition metal (1mk)





(ii) A complex anion containing a transition metal (1mk)





 2 marks

12.

Use the diagram below to answer the questions below:

Chemistry Paper 1 Question Paper - 2014 Cross Country Mock
(i) Identify gas Y (1mk)




(ii) Write an equation for the reaction taking place in the combustion tube. (1mk)





(iii) Which is the best place for carrying out the above experiment (1mk)




 3 marks

13.

400cm3 of Nitrogen gas diffuses through a porous plug in 70seconds. How long would it
take the same volume of Carbon (IV) oxide to diffuse through the same porous pot?
(C=12, O=16, N=14)






 3 marks

14.

20.0cm3 of NaOH solution containing 8.0gdm-3 were required for complete neutralization
of 0.118g of a dibasic acid. Calculate the Relative Molecular Mass (R.M.M) of the acid.
(Na=23, O=16, H=1)

 3 marks

15.

The diagram below shows the combustion of ethane gas. Study it and answer the questions
about it:

Chemistry Paper 1 Question Paper - 2014 Cross Country Mock

(a) Identify substance K (1mk)



(b) Write an equation for the complete combustion of ethane gas. (1mk)




(c) The pH of substance K is found to be less than 7. Explain this observation (1mk)




 3 marks

16.

The structure of hydrogen sulphide can be represented as shown below:

Chemistry Paper 1 Question Paper - 2014 Cross Country Mock
(a) Name the bond type represented by letters X and Y (2mks)




(b) Give a chemical test for hydrogen sulphide gas (1mk)




 3 marks

17.

In the Haber process, the industrial manufacture of ammonia is given by the following equation ;

Chemistry Paper 1 Question Paper - 2014 Cross Country Mock
(i) Name one source of hydrogen used in the process (1mk)




(ii) Name the catalyst used in the above reaction (1mk)





(ii) What is the effect of increasing temperature on yield of ammonia? Explain (1mk)





 3 marks

18.

The curves below were obtained when equal volumes of 2M HCl were reacted with 3.0g of marble chips (CaCO3). In one of the reactions, the acid was warmed before adding the marble chips.

Chemistry Paper 1 Question Paper - 2014 Cross Country Mock

(a) Write the equation for the reaction (1mk)




(b) Identify the curve representing the reaction where the acid was warmed. (1mk)




 2 marks

19.

Chlorine gas bubbled into a solution of hydrogen sulphide as shown below:

Chemistry Paper 1 Question Paper - 2014 Cross Country Mock
(i) Explain the observation made in boiling tube. (2mks)





(ii) What precautions should be taken in the experiment (1mk)





 3 marks

20.

Hydrogen fluorine reacts according to the equation,

Chemistry Paper 1 Question Paper - 2014 Cross Country Mock
(a) On the grid provided below, sketch the energy level diagram for the forward reaction (2mks)

Chemistry Paper 1 Question Paper - 2014 Cross Country Mock
(b) Calculate the molar heat of formation of HF (1mk)





(c) What will happen to the yield of HF when the temperature of the above system is
increased? (1mk)






 4 marks

21.

Study the physical properties of Magnesium and Beryllium. Use it to answer the questions
that follow:

Element Be Mg
MpoC
Bp oC
Atomic number
Atomic radius (nm)
1280
2450
4
0.086
650
1110
12
0.136

(a) Explain why Be has a higher m.p than Magnesium (2mks)





(b) Write the electron arrangement of Magnesium in the following compound; Mg3(PO4)2 (1mk)






 3 marks

22.

Study the diagram below and answer the questions that follow:

Chemistry Paper 1 Question Paper - 2014 Cross Country Mock
(i)What observation was made during the experiment. Explain? (1½mks)





(ii) What observation would be made if the solution of hydrogen in methylbenzene was
replaced with solution of hydrogen chloride in water? Explain (1½mks)






 3 marks

23.

Explain how you would prepare Aluminium hydroxide, staring with Aluminium sulphate.






 3 marks

24.

0.28g of iron burns in air to form Iron (II) oxide. Calculate the mass of Iron(II) oxide formed
(O=16, Fe=56)






 3 marks

25.

The table below gives the solubilities of Potassium Bromine and Potassium Sulphate at 00C
and at 400C;

Substance Solubility /100g water at 00C Solubility /100g water at 400C
Potassium Bromide 55 75
Potassium Sulphate 10 12

When aqueous mixture containing 60g of KB and 7g of K2SO4 in 100g water at 800C was
cooled to 00C, some crystals were formed;
(i) Identify the crystals (1mk)





(ii) Determine the mass of the crystals formed (1mk)






(iii) Name the method used to obtain the crystals (1mk)





(iv) Suggest one industrial application of the method named in (iii) above (1mk)





 4 marks

26.

State two environmental problems likely to be found in an area where Sulphur (IV) oxide is
Manufactured.






 2 marks

27.

Give two advantages of hard water.







 2 marks

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